Chemistry

Greener Fusion Energy Possible Thanks to Innovative Chemical Process

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Breakthrough in Clean Lithium-6 Production Could Accelerate Nuclear Fusion

A Mercury-Free Solution for Fusion’s Critical Fuel

Scientists have accidentally discovered a revolutionary method to isolate lithium-6—the rare isotope essential for nuclear fusion reactors—without using the toxic mercury-based process banned since the 1960s. This breakthrough could help solve one of fusion energy’s biggest supply chain challenges.

Why Lithium-6 Matters for Fusion Power

  • Tritium production: Lithium-6 generates tritium (fusion fuel) when bombarded by neutrons
  • Isotope scarcity: Makes up just 7.5% of natural lithium vs lithium-7’s 92.5%
  • Supply crisis: Global stockpiles are dwindling with no clean production method

The Accidental Discovery

Researchers at ETH Zurich stumbled upon the solution while developing membranes for oil-spill cleanup:

  • Used zeta vanadium oxide (a lab-made compound with oxygen-lined tunnels)
  • Noticed the material preferentially captured lithium-6 ions
  • Achieved separation without mercury or toxic chemicals

“The tunnels are just the right size to trap lithium-6,” explains lead researcher Sarbajit Banerjee. “It’s like a molecular sieve that selectively holds the isotope we need.”

3D render of a grassy globe a robot holding a solar panel to the sunlight

How the New Process Works

  1. Molecular filtration: Lithium ions flow through oxide tunnels
  2. Selective capture: Lithium-6 binds more strongly to tunnel walls
  3. Extraction: Purified lithium-6 can be harvested

While the team has only produced grams so far, the method shows potential for industrial-scale production—critical as future fusion plants may need tons daily.

Challenges Ahead

✔ Scaling up from lab to industrial quantities
✔ Optimizing efficiency of isotope separation
✔ Integrating with fusion reactor designs

“These are solvable problems compared to plasma containment challenges,” notes Banerjee.

Global Implications

  • Renews Western access to lithium-6 production
  • Eliminates mercury pollution risks
  • Could accelerate viable fusion power timelines

The discovery comes as ITER and private fusion companies race to demonstrate net energy gain, making this timely progress on a crucial fuel supply issue.

Next Steps: The team is working to improve yield and collaborate with fusion researchers to test the material in breeding blanket designs.


Source: ETH Zurich Materials Research
Image: Molecular structure of zeta vanadium oxide (rendering)

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